In Paris, the OPUR research programme created an experimental on-site observatory of urban pollutant loads in combined sewer systems in order to characterise the dry and wet weather flows at different spatial scales. This article presents the first results on the spatial variability of the polycyclic aromatic hydrocarbon (PAH) load during wet weather flow (WWF). At the scale of a rain event, investigations revealed that (i) PAH concentrations were relatively homogenous whatever the spatial scale and were greater than those of the dry weather flow (DWF), (ii) PAH distributions between dissolved and particulate phases were constant, and (iii) PAH fingerprints exhibited a similar pattern for all catchments. Moreover, an evaluation of the contribution of DWF, runoff and erosion of sewer deposits to WWF load was established. According to the hypothesis on the runoff concentration, the contributions were evaluated at 14, 8 and 78%, respectively, at the scale of the Marais catchment. For all the catchments, the runoff contribution was found quite constant and evaluated at approximately 10%. The DWF contribution seems to increase with the catchment area, contrary to the sewer erosion contribution, which seems to decrease. However, this latter still remains an important source of pollution. These first trends should be confirmed and completed by more investigations of rain events.